A water-soluble hexa-peri-hexabenzocoronene: synthesis, self-assembly and role as template for porous silica with aligned nanochannels.
نویسندگان
چکیده
A water-soluble hexa-peri-hexabenzocoronene was prepared and shown to undergo ordered columnar self-assembly either in water solution or bulk and therefore served as template for the fabrication of porous silica with aligned nanochannels.
منابع مشابه
Synthesis and sorption properties of hexa-(peri)-hexabenzocoronene-based porous organic polymers.
In this communication, we report the synthesis of several novel hexa-(peri)-hexabenzocoronene (HBC) containing microporous polymers. These polymers exhibit good adsorption properties for H2, N2 and CO2 gases. Based on fluorescence quenching studies, we have shown that the highly conjugated π-surfaces may be accessible by guests in solution.
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Hexaphenylbenzene (HPB) and hexa-peri-hexabenzocoronene-(HBC) functionalised 1,2,3-triazoles have been synthesised using an optimised copper(i)-catalysed azide-alkyne cycloaddition (CuAAC) reaction. The coordination chemistry of these ligands was explored through the synthesis of the respective palladium(ii) complexes and their activity as catalysts in the Suzuki-Miyaura reaction assessed.
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ورودعنوان ژورنال:
- Chemical communications
دوره 1 شماره
صفحات -
تاریخ انتشار 2006